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Journal of Environmental Accounting and Management
Dmitry Kovalevsky (editor), Jiazhong Zhang(editor)
Dmitry Kovalevsky (editor)

Climate Service Center Germany (GERICS), Helmholtz-Zentrum Hereon, Fischertwiete 1, 20095 Hamburg, Germany

Fax: +49 (0) 40 226338163 Email:

Jiazhong Zhang (editor)

School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, China

Fax: +86 29 82668723 Email:

Treatment of Highly Polluted Industrial Wastewater Utilizing Clean and Low Cost Technologies: Review Article

Journal of Environmental Accounting and Management 6(2) (2018) 167--184 | DOI:10.5890/JEAM.2018.06.007

Ibrahim Abdelfattah

Water Pollution Research Dept., National Research Centre, 33 EL Bohouth St., P.O. 12622, Dokki, Giza, Egypt

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A comprehensive review article dealing with clean and low cost technologies for treatment of highly polluted industrial wastewater will be detailed. These technologies covering: the biological processes including anaerobic methods with high production of biogas and lower production of sludge, aerobic methods will be excluded due to the higher sludge production and the added cost of aeration. Biosorption and adsorption processes including different clays and plant wastes will be included due to economic reasons and sustainability factors. Furthermore, advanced oxidation processes (AOPs) which are utilized in case of the higher ranges of toxic effluents as a cost effective technologies will be discussed. Solar processes which utilize the nature UV-source will be also involved. The review article is supported with case studies for relieving the noxious effects of wastewaters before discharging it into the surrounding environment. A valuable recommendations are presented to finalizing the review article drawing the best planning to get rid of the hazardous effects of the industrial effluents.


  1. [1]  Abdelfattah, I. (2011), Treatment of Liquid Hazardous Waste and Highly-Loaded Industrial Wastewater by photo-Fenton process including Noxiousness Assessment, Stuttgarter Berichte zur Abfallwirtschaft. ISBN 978-3-8356-3245-5, Germany.
  2. [2]  Abdelfattah, I., Al Sayed, F., and Almedolab, A. (2016a), Removal of Heavy Metals from Wastewater Using Corn Cob, Research Journal of Pharmaceutical, Biological and Chemical Sciences, 7, 239-248.
  3. [3]  Abdelfattah, I., Ismail, A.A., Al Sayed, F., Almedolab, A., and Aboelghait, K.M. (2016b), Biosorption of heavy metals ions in real industrial wastewater using peanut husk as efficient and cost effective adsorbent, Environmental Nanotechnology Monitoring & Management, 6, 176-183.
  4. [4]  Abou-Elela, S.I., Fawzy,M.E., and El-Gendy, A.S. (2015), Potential of using Biological Aerated Filter as a Post Treatment for MunicipalWastewater, Ecological Engineering, 84, 53-57.
  5. [5]  Achak, M., Hafidi, A., Ouazzani, N., Sayadi, S., and Mandi, L. (2009), Low cost biosorbent "banana peel" for the removal of phenolic compounds from olive mill wastewater: Kinetic and equilibrium studies, Journal of Hazardous Materials, 166, 117-125.
  6. [6]  Adie, D.B., Okuofu, C.A., and Osakwe, C. (2012), Comparative Analysis of the Adsorption of Heavy Metals inWastewater Using Borrassus Aethiopium and Cocos Nucifera, International Journal of Applied Science and Technology, 2(7), 314- 322.
  7. [7]  Aksu, Z. and Yener, J. (2001), A comparative adsorption/biosorption study of monochlorinated phenols onto various sorbents, Waste Management, 21(8), 695-702.
  8. [8]  Amirnia, S. (2015), PhD-Thesis. Biosorption Processes for Removal of Toxic Metals from Wastewaters, The School of Graduate and Postdoctoral Studies, The University ofWestern Ontario, Canada.
  9. [9]  Ara, B., Shah, J., Jan, M.R., and Aslam, S. (2013), Removal of Metribuzin Herbicide from Aqueous Solution using Corn Cob, International Journal of Science, Environment and Technology, 2(2), 146-161.
  10. [10]  Arief, V.O., Trilestari, K., Sunarso, J., Indraswati, N., and Ismadji, S. (2008), Recent progress on biosorption of heavy metals from liquids using low cost biosorbents: Characterization, biosorption parameters and mechanism studies: a review, Clean Soil Air Water, 36, 937-962.
  11. [11]  Arunkumar, C., Perumal, R., and Lakshmi, S.N. (2014), Use of Corn cob powder as Low Cost Adsorbent for the Removal of Nickel (II) From Aqueous Solution, International Journal of Advanced Biotechnology and Research, 5(3), 325-330.
  12. [12]  Bakir, A., Mcloughlin, P. and Fitzgerald, E. (2010), Regeneration and reuse of a seaweed based biosorbent in single and multi-metal systems, Clean Soil Air Water, 38, 257-262.
  13. [13]  Bhatnagar, A., Minochaa, A.K., and Sillanp, M. (2010), Adsorptive removal of cobalt from aqueous solution by utilizing lemon peel as biosorbent, Biochemical Engineering Journal, 48, 181-186.
  14. [14]  Blanco, J., Malato, S., Fernández-Ibañez, P., Alarcón, D., Gernjak, W. and Maldonado, M.I. (2009), Review of feasible solar energy applications to water processes, Renewable and Sustainable Energy Reviews, 13(6-7), 1437-1445.
  15. [15]  Boucher, J., Steiner, L., andMarison, I.W. (2007), Bio-sorption of atrazine in the press-cake from oilseeds, Water Research, 41(15), 3209-3216.
  16. [16]  Bulut, Y. and Tez, Z. (2007), Removal of heavy metals from aqueous solution by sawdust adsorption, Journal of Environmental Science, 19, 160-166.
  17. [17]  Chan, P.Y., Gamal El-Din, M., and Bolton, J.R. (2012), A solar-driven UV/chlorine advanced oxidation process, Water Research, 46, 5672-5682.
  18. [18]  Chan, Y.J., Chong, M.F., Law, C.L., and Hassell, D.G. (2009), A review on anaerobic-aerobic treatment of industrial and municipal wastewater, Chemical Engineering Journal, 155, 1-18.
  19. [19]  Corseuil, H.X., Monier, A.L., Fernandes, M., Schneider, M.R., Nunes, C.C., do Rosario, M., and Alvarez, P.J.J. (2011), BTEX plume dynamics following an ethanol blend release: geochemical footprint and thermodynamic constraints on natural attenuation, Environmental Science and Technology, 45, 3422-3429.
  20. [20]  Durán, A., Monteagudo, J.M., Sanmartín, I., and García-Díaz, A. (2013), Sonophotocatalytic mineralization of antipyrine in aqueous solution, Applied Catalysis B: Environmental, 138-139, 318-325.
  21. [21]  Egila, J.N., Dauda, B.E.N., and Jimoh, T. (2010), Biosorptive removal of cobalt (II) ions from aqueous solution by Amaranthus hydridus L. stalk wastes, African Journal of Biotechnology, 9(48), 8192-8198.
  22. [22]  El-Awady, M.H., Abdelfattah, I., and Abo El-Magd, A. (2015), Reliable Treatment of Petroleum Processing Wastewater Using Dissolved Air Flotation in Combination with Advanced Oxidation Process, Egyptian Journal of Chemistry, 58(6), 609-624.
  23. [23]  El-Gohary, F.A. and Nasr, F.A. (1999), Cost-effective pre-treatment of wastewater, Water Scince and Technology, 39(5), 97-103.
  24. [24]  El-Sayed, G.O., Dessouki, H.A., and Ibrahim, S. (2011), Removal of Zn(II), Cd(II), Mn(II) from aqueous solution by adsorption on maize stalks, The Malaysian Journal of Analytical Sciences, 15, 8-21.
  25. [25]  Esparza, S.M., Solís, M.C., and Hernández, T.J.J. (2011), Anaerobic treatment of a medium strength industrial wastewater at low-temperature and short hydraulic retention time: a pilot-scale experience, Water Science and Technology, 64(8), 1629-1635.
  26. [26]  Fia, F.R.L., Matos, A.T., Borges, A.C., Fia, R., and Cecon, P.R. (2012), Treatment of wastewater from coffee bean processing in anaerobic fixed bed reactors with different support materials: performance and kinetic modeling, Journal of Environmental Management, 108, 14-21.
  27. [27]  Foletto, E., Battiston, S., Collazzo, G., Bassaco,M., andMazutti, M. (2012), Degradation of leather dye using CeO2-SnO2 nanocomposite as photocatalyst under sunlight, Water, Air and Soil Pollution, 223, 5773-5779.
  28. [28]  Freitas, A.M., Sirtori, C., Lenz, C.A., and Peralta Zamora, P.G. (2013),Microcystin-LR degradation by solar photo-Fenton, UV-A/photo-Fenton and UV-C/H2O2: a comparative study, Photochemical & Photobiological Sciences, 12, 696-702.
  29. [29]  Freundlich, H.M.F. (1906), Über die Adsorption in Lösungen, Zeitschrift für Physikalische Chemie, 57, 385-470.
  30. [30]  Frontistis, Z., Drosou, C., Tyrovola, K., Mantzavinos, D., Fatta-Kassinos, D., Venieri, D., and Xekoukoulotakis, N.P.(2012), Experimental and modeling studies of the degradation of estrogen hormones in aqueous TiO2 suspensions under simulated solar radiation, Industrial & Engineering Chemistry Research, 51, 16552-16563.
  31. [31]  Fujishima, A., Zhang, X., and Tryk, D.A. (2007), Heterogeneous photocatalysis from water photolysis to applications in environmental cleanup, International Journal of Hydrogen Energy, 32, 2664-2672.
  32. [32]  Garcia-Garcia, A., Martinez-Mirand, V., Martinez-Cienfuegos, I.G., Almazan-Sanchez, P.T., Castaneda-Juarez, M., and Linares-Hernandez, I. (2015), Industrial wastewater treatment by electrocoagulation-electrooxidation processes pow ered by solar cells, Fuel, 149, 46-54.
  33. [33]  Gonçalves,M.R., Costa, J.C., Marques, I.P., and Alves, M.M. (2012), Strategies for lipids and phenolics degradation in the anaerobic treatment of olive mill wastewater, Water Research, 46, 1684-1692.
  34. [34]  Gonçalves, M.R., Freitas, P., and Marques, I.P. (2012), Bioenergy recovery from olive mill effluent in a hybrid reactor, Biomass and Bioenergy, 39, 253-260.
  35. [35]  Hashim, M.A., Tan, H.N., and Chu, K.H. (2000), Immobilized marine algal biomass for multiple cycles of copper adsorption and desorption, Separation and Purification Technology, 19, 39-42.
  36. [36]  Ibrahim, M.B. (2013), Thermodynamics and adsorption efficiencies of maize cob and Sawdust for the remediation of toxic metals from wastewater, Journal of Geosciences and Environment Protection, 1, 18-21.
  37. [37]  Inel, O., Albayrak, F., and Askin, S. (1998), Cu and Pb Adsorption on Some Bentonitic Clays, Turkish Journal of Chemistry, 22, 243-252.
  38. [38]  Ismail, A.A., Abdelfattah, I., Atitar, M.F., Robben, L., Bouzid, H., Al-Sayari, S.A., and Bahnemann, D.W. (2015), Photocatalytic degradation of imazapyr using mesoporous Al2O3-TiO2 nanocomposites, Separation and Purification Technology, 145, 147-153.
  39. [39]  Ismail, A.A., Abdelfattah, I., Helal, A., Al-Sayari, S.A., Robben, L., and Bahnemann, D.W. (2016), Ease synthesis of mesoporous WO3-TiO2 nanocomposites with enhanced photocatalytic performance for photodegradation of herbicide imazapyr under visible light and UV illumination, Journal of Hazardous Materials 307, 43-54.
  40. [40]  Jalali, R., Ghafourian, H., Asef, Y., Davarpanah, S.J., and Sepehr, S. (2002), Removal and recovery of lead using nonliving biomass of marine algae, Journal of Hazardous Materials B92, 253-262.
  41. [41]  Jamil, N. andMunwar,M.A. (2009), Biosorbtion of Hg(II) and Cd(II) from waste water by using ZeaMays waste, Journal of the Chemical Society of Pakistan, 31(3), 362-369.
  42. [42]  Jonathan, Y., Hussaina, H., and Tijani, J.O. (2011), Application of adsorbent from Dum palm for the removal ofManganese (II), Zinc (II) and Copper (II) ions from aqueous solution, Journal of American Science, 7(10), 226-230.
  43. [43]  Langmuir, I. (1916), The constitution and fundamental properties of solids and liquids, Journal of the American Chemical Society, 38, 2221-2295.
  44. [44]  Lau, T.C., Ang, P.O., and Wong, P.K. (2003), Development of seaweed biomass as a biosorbent for metal ions, Water Science and Technology, 47, 49-54.
  45. [45]  Lemić, J., Kovacević, D., Tomasević-Canović, M., Kovacević, D., Stanić, T., and Pfend, R. (2006), Removal of atrazine, lindane and diazinone from water by organo-zeolites,Water Research 40(5), 1079-1085.
  46. [46]  Malato, S., Fernandez-Ibanez, P., Maldonado, M.I., Blanco, J., and Gernjak,W. (2009), Decontamination and disinfection of water by solar photocatalysis: Recent overview and trends, Catalysis Today 147, 1-59.
  47. [47]  Marcelino, R.B.P., Queiroz, M.T.A., Amorim, C.C., Le?ao, M.M.D., and Brites, F.F. (2015), Solar energy for wastewater treatment: review of international technologies and their applicability in Brazil, Environmental Science and Pollution Research, 22(2), 762-773.
  48. [48]  Marín, P., Alkalay, D., Guerrero, L., Chamy, R., and Schiappacasse, M.C. (1999), Design and startup of an anaerobic fluidized bed reactor, Water Science and Technology, 40(8), 63-70.
  49. [49]  Michael, I., Hapeshi, E., Ace, N.J., Perez, S., Petrovic, M., Zapata, A., Barcelo, D., Malato, S., and Fatta-Kassinos, D.(2013), Light-induced catalytic transformation of ofloxacin by solar Fenton in various water matrices at a pilot plant: mineralization and characterization of major intermediate products, Science of Total Environment, 461-462, 39-48.
  50. [50]  Mico, M.M., Bacardit, J., Malfeito, J., and Sans, C. (2013), Enhancement of pesticide photoFenton oxidation at high salinities, Applied Catalysis B: Environmental, 132-133, 162-169.
  51. [51]  Monteagudo, J.M., Duran, A., Corral, J.M., Carnicer, A., Frades, J.M., and Alonso, M.A. (2012), Ferrioxalate-induced solar photo-Fenton system for the treatment of winery wastewaters, Chemical Engineering Journal, 181-182, 281-288.
  52. [52]  Munter, R. (2001), Advanced oxidation processes-current status and prospects, Proceedings of the Estonian Academy of Sciences, 50(2), 59-80.
  53. [53]  Muthusamy, P., Murugan, S., and Manothi, S. (2012), Removal of Nickel ion from industrial wastewater using maize cob, ISCA Journal of Biological Sciences, 1(2), 7-11.
  54. [54]  Musapatika, E.T., Singh1, R., Moodley, K., Nzila, C., Onyango, M.S., and Ochieng, A. (2012), Cobalt removal from wastewater using pine sawdust, African Journal of Biotechnology, 11(39), 9407-9415.
  55. [55]  Nascimento, C.A.O., Teixeira, A.C., Guardani, R., Quina, F.H., Chiavone-Filho, O., and Braun, A.M. (2007), Industrial Wastewater Treatment by Photochemical Processes Based on Solar Energy, Journal of Solar Energy Engineering, 129, 45-52.
  56. [56]  Nasr, F.A., Badr, N.M., Doma, H.S., and El-Shafai, S.A. (2006), Chemical industry wastewater treatment, The Environmentalist, 26(1), 31-39.
  57. [57]  Nasr, F.A., Doma, H.S., Abdel-Halim, H.S., and El-Shafai, S.A. (2007), Chemical industry wastewater treatment, The Environmentalist, 27(2), 275-286.
  58. [58]  Nezamzadeh-Ejhieh, A. and Banan, Z. (2011), A comparison between the efficiency of CdS nanoparticles/zeolite A and CdO/zeolite-A as catalysts in photodecolorization of crystal violet, Desalination, 279, 146-15.
  59. [59]  Pera-Titus, M., Garcia-Molina, V., Banos, M.A., Gimenez, J., and Esplugas, S. (2004), Degradation of chlorophenols by means of advanced oxidation processes: a general review, Applied Catalysis B: Environmental, 47, 219-256.
  60. [60]  Pérez, J.A.S., Lopez, J.L.C., and Malato, S. (2013), Economic evaluation of a combined photo-Fenton/MBR process using pesticides as model pollutant. Factors affecting costs, Journal of Hazardous Materials, 244-245, 195-203.
  61. [61]  Petrovic, M., Radjenovic, J., and Barcelo, D. (2011), Advanced oxidation processes (AOPs) applied for wastewater and drinking water treatment. Elimination of pharmaceuticals. In: The Holistic Approach to Environment, 1, 63-74.
  62. [62]  Perez, M., Romero, L.I., and Sales, D. (1999), Anaerobic thermophilic fluidized bed treatment of industrial wastewater: effect of F:M relationship, Chemosphere, 38(14), 3443-3461.
  63. [63]  Prieto-Rodriguez, L., Oller, I., Klamerth, N., Aguera, A., Rodriguez, E.M. and Malato, S. (2013), Application of solar AOPs and ozonation for elimination of micropollutants in municipal wastewater treatment plant effluents, Water Research, 47, 1521-1528.
  64. [64]  Quan, X.,Wang,W., Yang, Z., Lin, C. and He, M. (2007), Continuous removal of aromatic hydrocarbons by an AF reactor under denitrifying conditions, World Journal of Microbiology and Biotechnology, 23(12), 1711-1717.
  65. [65]  Rajagopal, R., Saady, N.M.C., Torrijos, M., Thanikal, J.V., and Hung, Y. (2013), Review Sustainable Agro-Food Industrial Wastewater Treatment Using High Rate Anaerobic Process, Water, 5, 292-311.
  66. [66]  Rajeshwari, K.V., Balakrishnan, M., Kansal, A., Lata, K. and Kishore, V.V.N. (2000), State of the art of anaerobic digestion technology for industrial wastewater treatment, Renewable and Sustainable Energy Reviews, 4, 135-156.
  67. [67]  Rajinikanth, R., Ganesh, R., Escudie, R., Mehrotra, I., Kumar, P., Thanikal, J.V. and Torrijos, M. (2009), High rate anaerobic filter with floating supports for the treatment of effluents from small-scale agro-food industries, Desalination and Water Treatment, 4, 183-190.
  68. [68]  Robert, D. and Malato, S. (2002), Solar photocatalysis: a clean process for water detoxification, Science of the Total Environment, 291(1-3), 85-97.
  69. [69]  Rocha, E.M.R., Vilar, V.J.P., Fonseca, A.L., Saraiva, I. and Boaventura, R.A.R. (2011), Landfill leachate treatment by solar-driven AOPs, Solar Energy, 85, 46-56.
  70. [70]  Rodriguez, E.M., Fernandez, G., Klamerth, N., Maldonado, M.I., Alvarez, P.M. and Malato, S. (2010), Efficiency of different solar advanced oxidation processes on the oxidation of bisphenol A in water, Applied Catalysis B: Environmental, 95, 228-237.
  71. [71]  Saien, J. and Nejati, H. (2007), Enhanced photocatalytic degradation of pollutants in petroleum refinery wastewater under mild conditions, Journal of Hazardous Materials, 148, 491-495.
  72. [72]  Sari, A. and Tuzen, M. (2009), Kinetic and equilibrium studies of biosorption of Pb(II) and Cd(II) from aqueous solution by macro fungus (Amanita rubescens) biomass, Journal of Hazardous Materials, 164(2-3), 1004-1011.
  73. [73]  Sari, A., Tuzen, M., Uluozlu, O.D., and Soylak, M. (2007), Biosorption of Pb(II) and Ni(II) from aqueous solution by lichen (Cladoniafurcata) biomass, Biochemical Engineering Journal, 37(2), 151-158.
  74. [74]  Sent“urk, E., Ince, M., and Engin, G.O. (2010), Treatment efficiency and VFA composition of a thermophilic anaerobic contact reactor treating food industry wastewater, Journal of Hazardous Materials, 176(1-3), 843-848.
  75. [75]  Sharon, H. and Reddy, K.S. (2015), A review of solar energy driven desalination technologies, Renewable and Sustainable Energy Reviews, 41, 1080-1118.
  76. [76]  Stasinakis, A. (2008),Use of selected advanced oxidation processes (AOPs) for wastewater treatment-a mini review, Global Nest Journal, 10, 376-385.
  77. [77]  Sud, D., Mahajan, G., and Kaur, M.P. (2008), Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions - A review, Bioresource Technology, 99, 6017-6027.
  78. [78]  Sun, L., Wan, S., Yu, Z., Wang, Y., and Wang, S. (2012), Anaerobic biological treatment of high strength cassava starch wastewater in a new type up-flow multistage anaerobic reactor, Bioresource Technology, 104, 280-288.
  79. [79]  van Haandel, A. and van der Lubbe, J. (2012), (Book) Handbook of Biological Wastewater Treatment: Second Edition. IWA publishing books ISBN 13: 9781780407753.
  80. [80]  Vilar, V.J.P., Capelo, S.M.S., Silva, T.F.C.V., and Boaventura, R.A.R. (2011), Solar photoFenton as a pre-oxidation step for biological treatment of landfill leachate in a pilot plant with CPCs, Catalysis Today, 161, 228-234.
  81. [81]  Won, S.G., Lau, A.K. (2011), Effects of key operational parameters on biohydrogen production via anaerobic fermentation in a sequencing batch reactor, Bioresource Technology, 102(13), 6876-6883.
  82. [82]  Yan, C., Yan, G.Y., Xue, P., Wei, Q., and Li, Q. (2010), Competitive effect of Cu(II) and Zn(II) on the biosorption of lead(II) by Myriophyllum spicatum, Journal of Hazardous Materials, 179, 721-728.
  83. [83]  Zhang, T., Wang, X., and Zhang, X. (2014), Review Article: Recent Progress in TiO2 Mediated Solar Photocatalysis for IndustrialWastewater Treatment, International Journal of Photoenergy, 2014, 1-12.
  84. [84]  Zheng, S., Yang, Z., Jo, D.H., and Park, Y.H. (2004), Removal of chlorophenols from groundwater by chitosan sorption, Water Research, 38, 2315-2322.
  85. [85]  Zheng, S., Yang, M., Yang, Z., and Yang, Q. (2005), Biomass production from glutamate fermentation wastewater by the co-culture of Candida halophila and Rhodotorula glutinis, Bioresource Technology, 96, 1522-1524.